We refactored the errors returned from OPENTCP and any of the instructions that use a TCP connection (HTTPCMD, EMAIL), with the specific intention of distinguishing between connections that were dropped by the server vs those that never succeeded. Previously both of those used a generic "something broke" error. The 64 code means that the connection was never established to begin with, and somebody (read: Yours Truly) forgot to add an error description to the appropriate table. So basically the controller isn't getting the answer from the server.
FF:FF:FF:FF:FF:FF is the broadcast address, which means that a valid TCP address either wasn't provided, the ARP didn't work, or the DNS came back with something jacked up.