After following up with the tech that got this straightened out:
1) We are not sure exactly how, why or what got screwed up on the IO map or IP address so this one remains a "shrugging of the shoulders."
2) My coworker proved to his satisfaction that the only reliable way to power up the racks was pretty much simultaneously. There could be a few seconds difference, but not much and it made no difference whether the processor or slave was first if the interval between was more than that few seconds. Outside of this, the slave rack was missing in action.
3) The power was reworked to have the processor power and both slaves to all be from the same circuit breaker in the main panel.
I used manual addressing to prevent stupid I/O reassignment if a card was pulled, swapped or a rack didn't power up. (Sorry, but automatic I/O assignment only looks great on the drawing board; in real life it is asking for disaster.*)
* Did I get the semicolon right?