The 205 PLC line has 2 different CPU types, but same I/O.
DirectLOGIC (30 year old technology, octal addressing, 1 block of numeric that contains BCD, Real, decimal, etc. that also maps to I/O, and one block of memory bits. It does Modbus through mapping of octal V addressing to Modbus memory, and the I/O is exposed (Modbus master can directly manipulate I/O).
Do-more is more recent and supports Modbus as a Slave natively through Modbus memory (do not confused MRX/MWX where Do-more is the Master). There is no direct access to I/O, just internal "Modbus" data blocks.
Since you have a PC that is the Master, the PC will look at Modbus Coil memory (MC), Modbus Input memory (MI), Modbus Input Register memory (MIR) and Modbus Holding Register memory (MHR) - NATIVELY. No mapped V. No mapped octal addressing to decimal stuff. No spreadsheet (don't ask).
In Do-more Modbus memory offsets start at 1, e.g. Modbus Holding Register 40001 maps to MHR1. Modbus Input Register 30001 maps to MIR1. Modbus Coil 00001 map to MC1. Modbus (discrete) Input 10001 maps to MI1.
So, from your PC, you write to Holding Register 40001, that data ends up in MHR1. If you want that to be an analog output, say WY0, use a MOVE instruction to copy MHR1 to WY0. Your PC, when it writes to 40001, will write to MHR1 and that value get copied to analog output WY0 via ladder logic.
Say you want Input Register 30007 to be a Timer Accumulator T2.Acc, use a MOVE instruction to copy T2.Acc to MIR7. When the PC reads Input Register 30007, it will get that timer accumulator value.
Rather than do a bunch of MOVE's, I recommend sticking your INPUT logic in $tTopOfScan code-block, inside a single table based COPY instruction. Similarly, stick your OUTPUT logic in $tBottomOfScan code-block in another COPY instruction. COPY is a nice compact table based "move" where you can easily copy lists of blocks of values. Very compact.
If for some reason you need to swap words or do BCD, look at PUBLISH (for outputs) and SUBSCRIB (for inputs) to get the data in the desired format from/to Do-more to what your PC needs.